CRA generally starts charging interest a month after the payment was due. So, for example, a 2024 personal tax balance that was due April 30, 2025 will start to accrue interest May 1, but generally won’t be APPLIED to the balance until June 1. See here:
The process to ask for interest to be waived is called “Taxpayer relief”. You have to fill out and send them a RC-4288: